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1.
《International Journal of Hydrogen Energy》2021,46(73):36301-36313
By choosing a triple block polymer, poly(styrene-b-(ethylene-co-butylene)-b-styrene) (SEBS), as the backbone and adopting a long side-chain double-cation crosslinking strategy, a series of SEBS-based anion-exchange membranes (AEMs) was successively synthesized by chloromethylation, quaternization, crosslinking, solution casting, and alkalization. The 70C16-SEBS-TMHDA membrane showed high OH− conductivity (72.13 mS/cm at 80 °C) and excellent alkali stability (only 10.86% degradation in OH− conductivity after soaking in 4-M NaOH for 1700 h at 80 °C). Furthermore, the SR was only 9.3% at 80 °C and the peak power density of the H2/O2 single cell was up to 189 mW/cm2 at a current density of 350 mA/cm2 at 80 °C. By introducing long flexible side chains into a polymer SEBS backbone, the structure of the hydrophilic–hydrophobic microphase separation in the membrane was constructed to improve the ionic conductivity. Additionally, network crosslinked structure improved dimensional stability and mechanical properties. 相似文献
2.
A study of the secondary source phenomenon due to the presence of off-focal radiation in industrial micro-focus cone-beam X-ray computed tomography (XCT) systems and its influence on dimensional measurements is presented. Although off-focal radiation production within X-ray tubes has been studied for medical X-ray imaging systems, its properties and its effects on dimensional measurements in industrial XCT systems have not been discussed prior to this research. The study comprises: evaluation of the geometrical properties of off-focal radiation through a theoretical and experimental study of two-dimensional projection images of the scanned objects, verification of these properties using computer simulations and evaluation of the impact of the secondary source on dimensional measurements using experimental and simulation approaches. In addition, ways to minimise the effects of off-focal radiation are discussed, and reference samples for characterising the properties of off-focal radiation are proposed. 相似文献
3.
High dimensionality in real-world multi-reservoir systems greatly hinders the application and popularity of evolutionary algorithms, especially for systems with heterogeneous units. An efficient hierarchical optimization framework is presented for search space reduction, determining the best water distributions, not only between cascade reservoirs, but also among different types of hydropower units. The framework is applied to the Three Gorges Project (TGP) system and the results demonstrate that the difficulties of multi-reservoir optimization caused by high dimensionality can be effectively solved by the proposed hierarchical method. For the day studied, power output could be increased by 6.79 GWh using an optimal decision with the same amount of water actually used; while the same amount of power could be generated with 2.59 × 107 m3 less water compared to the historical policy. The methodology proposed is general in that it can be used for other reservoir systems and other types of heterogeneous unit generators. 相似文献
4.
为将我国最严格水资源管理制度的实践与二元水循环理论相结合,提高“三条红线”控制指标的科学性与合理性,本文以SWAT模型为基础,通过改进子流域划分方法、添加经济社会模块和人工用水模块,对其人工侧支循环模拟进行了系统的完善,开发了基于SWAT的水量-水质-水效联合调控模型SWAT_WAQER。以广西南流江流域为例,从国民经济用水量、河道径流与水质等方面对模型进行校验,并在此基础上划分了2030年“三条红线”控制指标。结果表明:该模型性能良好,能够用于不同节水情景下的国民经济用水量、污染物排放量、水功能区水质达标结果分析,可以作为科学制定“三条红线”控制指标的有力支撑工具。 相似文献
5.
S. David Graber 《Canadian Metallurgical Quarterly》2004,130(1):67-80
Numerous types of pipes and channels with spatially increasing flows in environmental engineering applications are identified by type and function and referred to as collection conduits. An overview of methods for designing and analyzing collection conduits is provided. Full conduits with nonuniform and uniform inflow are first considered. Dimensional analysis is then employed to demonstrate the relationship between variables for open channels; that leads to the identification of possibilities for generalized numerical solutions. Prior collection conduit applications are discussed within the framework of the dimensional analysis (which also pertains to some constant-flow applications). A previously unpublished generalized numerical solution for rectangular collection conduits is presented. Subsurface drains are addressed with particular emphasis, including the use of numerical methods to develop a new generalized chart and relation to other design methods. Among the important conclusions for subsurface drains is that the somewhat common practice of using Manning’s equation alone for such problems is not generally adequate. Examples and practical design suggestions are included, and the use of computer-based numerical methods is discussed more generally. 相似文献
6.
三峡三期工程主坝大体积混凝土内部温度控制 总被引:2,自引:2,他引:0
三峡右岸三期工程施工中,为了有效控制坝体大体积混凝土内部温升,采取了高温季节使用预冷混凝土浇筑、控制混凝土出机口温度及浇筑温度、对混凝土内部人工通水进行初冷、中冷和后冷等措施。三峡三期工程大坝混凝土内部温度没有出现超标现象,混凝土温控工作取得了良好的效果。 相似文献
7.
本文介绍了三峡工程进入2002年后工程建设的新特点,并对工程下一步两个重点项目三期截流和碾压混凝土围堰的技术难点和工期安排做了深入分析。另外,作者根据国家电力体制改革的重要内容,以及中国三峡总公司自身情况,对公司未来的可持续发展之路亦做了深入探讨。借助中国三峡总公司的品牌优势和资本实力,吸收其它形式的能源,优化能源结构;进一步降低工程造价,提高三峡电价在电力市场的竞争力;依靠科学管理,实现电力生产利润最大化,深化内部改革等措施,促进中国三峡总公司可持续发展。 相似文献
8.
三峡水库减淤增容调度方式研究——多汛限水位调度方案 总被引:8,自引:0,他引:8
本文建议在汛期中小流量时(Q<35000m3/s),将坝前水位维持在148~151m;出现汛情且流量更较大后,将坝前水位降低到143m;入库流量大于35000m3/s且短期预报将出现大于十年一遇洪水时,预泄洪水到135m.按这一调度,汛期约80%时间可以维持在较高水位,一般洪水期。汛限水位143m不影响坝区通航,135m水位迎洪可大量增加防洪库客。到100年后可减淤30亿m3,增加防洪库容约40亿m3.变动回水区减淤40%,优化了坝区水沙搭配,可改善通航条件。降低库区洪水位,缓解防洪与移民的矛盾。可对发电带来较大好处:提高发电效益,减少粗沙过机。初期水库排沙比大于原方案,可减轻下游冲刷。同时,可减小三峡汛初泄水与鄱阳湖防洪的矛盾。 相似文献
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